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metal-organic compounds
The title complex, [K(C14H20O5)2]2[Zn(C3S5)2] or [K(B-15-C-5)2]2[Zn(dmit)2] (B-15-C-5 = benzo15-crown-5 and dmit = 4,5-dimercapto-1,3-dithiole-2-thione), contains two {[K(B-15-C-5)2]2}+ complex cations and one [Zn(dmit)2]2− complex anion in the asymmetric unit. The complex has a three-dimensional network structure assembled by intermolecular S
S and weak C—HS interactions.
S and weak C—HS interactions.metal-organic compounds
In the title complex, [Cu(C12H12N2O3)(C5H5N)], the CuII atom has a square-planar coordination geometry, formed by the tridentate hydrazone and the monodentate pyridine ligands. The distance of 3.706 (4) Å between the centroids of the nearly parallel [dihedral angle 4.9 (5)°] pyridine ring and the benzene ring of a neighbouring complex molecule suggests the existence of π–π stacking.
