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The title complex, [K(C14H20O5)2]2[Zn(C3S5)2] or [K(B-15-C-5)2]2[Zn(dmit)2] (B-15-C-5 = benzo15-crown-5 and dmit = 4,5-dimercapto-1,3-dithiole-2-thione), contains two {[K(B-15-C-5)2]2}+ complex cations and one [Zn(dmit)2]2− complex anion in the asymmetric unit. The complex has a three-dimensional network structure assembled by inter­molecular S...S and weak C—H...S inter­actions.
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