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The tetra­dentate Schiff base ligand derived from the condensation of 3,5-dibromo­salicylaldehyde and 1,2-phenyl­enediamine, in the presence of pyridine, forms a square-pyramidal five-coordinate Zn complex, [Zn(C20H10Br4N2O2)(C5H5N)]·C3H7N0.
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