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In the structure of caesium chloride 2-(N-morpholinio)­ethane­sulfonate, Cs+·Cl-·C6H13NO4S, determined by X-ray diffraction analysis at 100 K, the caesium cation is coordinated by the chloride anion and six O atoms.

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The six-membered ring of the title compound, C16H23BrO10, adopts a chair conformation. The mol­ecules are interconnected by weak C—H...O hydrogen bonds into a three-dimensional network.

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The title compound (systematic name: 4-amino-2-thioxo-2,3-dihydro­pyrimidin-1-ium chloride), C4H6N3S+·Cl, has two cations and two anions in the asymmetric unit. The two cations have nearly the same structure. Both are nearly planar, the largest distance from the non-H atoms to the least-squares plane through the six-membered ring atoms being 0.010 (2) Å. Both Cl ions serve as hydrogen-bond acceptors. One thiocytosinium cation forms N—H...Cl hydrogen bonds with three Cl anions and the other one with four Cl ions, giving a sheet parallel to (101). There is also an N—H...S inter­molecular hydrogen bond.

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The structure of the title compound (systematic name: 6-amino-2-thioxo-2,3-dihydro­pyrimidin-1-ium bromide), C4H6N3S+·Br-, has two 2-thio­cytosinium cations and two Br- anions in the asymmetric unit and is isostructural with 2-thio­cytosinium chloride. Both six-membered rings are essentially planar. S atoms and Br- anions serve as hydrogen-bond acceptors, forming sheets parallel to (101).
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