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The title compound (systematic name: aqua{4,4'-di­bromo-2,2'-[1,2-ethanediyl­bis­(nitrilo­methyl­idyne)]­diphenolato]­chloro­manganese(III)), [Mn(C16H12Br2N2O2)Cl(H2O)] or [Mn(Br2salen)Cl(H2O)], was prepared from a methanol solution. The Mn3+ ion displays an elongated octahedral geometry, coordinated by two N and two O atoms from salen, one O atom from the water ligand and one Cl- anion, and is slightly displaced out of the Schiff base N2O2 plane toward the axial Cl- ion. Hydro­gen bonds between the coordinated water O and Cl atoms link pairs of mol­ecules into a three-dimensional network.
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