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The reaction of terephthalo­nitrile and sodium azide catalyzed by manganese chloride tetrahydrate converts one nitrile group to tetrazole and leaves the other nitrile group unchanged. The MnII atom in the title compound, [Mn(H2O)6](C8H4N5)2, is coordinated by six water mol­ecules and lies on a position of 2/m crystallographic symmetry. The plane of the tetrazolate anion is perpendicular to a crystallographic mirror plane.
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