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The title compound, poly­[[rubidium-μ-5-sulfonosalicylic acid] monohydrate], Rb+·C7H5O6S·H2O, the 5-sulfosalicylic acid anion (3-carboxy-4-hydroxy­benzene­sulfonate) has lost the proton of —SO3H group, but retains the usual intermolecular hydrogen bond between the phenolic and carboxyl­ic O atoms. The Rb+ cation is surrounded by eight O atoms. The crystal packing is stabilized by intermolecular O—H...O hydrogen bonds.
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