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In the title compound, [Ni(C9H10NO2)2(H2O)2], the coordination geometry around the NiII ion can be described as distorted octa­hedral, with two N atoms and two O atoms from phenyl­alaninate ligands in the basal plane and two aqua O atoms at the axial sites. The crystal packing is stabilized by inter­molecular O—H...O and N—H...O hydrogen bonds.

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In the title mol­ecule, C14H13IN2O3S, the dihedral angle between the planes of the benzene and toluene rings is 84.3 (3)°. The mol­ecule displays a trans conformation with respect to the C=N bond. There is an intra­molecular O—H...N hydrogen bond with the azomethine N atom as acceptor. In the crystal, N—H...O hydrogen bonds connect the mol­ecules into chains running along the b axis.
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