metal-organic compounds
Open access
In the title compound, [Ni(C9H10NO2)2(H2O)2], the coordination geometry around the NiII ion can be described as distorted octahedral, with two N atoms and two O atoms from phenylalaninate ligands in the basal plane and two aqua O atoms at the axial sites. The crystal packing is stabilized by intermolecular O—HO and N—HO hydrogen bonds.
organic compounds
Open access
In the title molecule, C14H13IN2O3S, the dihedral angle between the planes of the benzene and toluene rings is 84.3 (3)°. The molecule displays a trans conformation with respect to the C=N bond. There is an intramolecular O—HN hydrogen bond with the azomethine N atom as acceptor. In the crystal, N—HO hydrogen bonds connect the molecules into chains running along the b axis.