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In the title compound, [Ni(C6H3ClNO2)2(H2O)4]·4H2O, the NiII ion is located on an inversion centre and is octa­hedrally coordinated by four O atoms from four water mol­ecules in the equatorial plane and two O atoms of two 6-chloro-3-carboxyl­ate ligands in axial positions. There are also four lattice water molecules present. The organic ligands are bound to the NiII ion in a monodentate manner through a carboxyl­ate O atom. There is one strong intra­molecular O—H...O hydrogen bond and six inter­molecular O—H...O and O—H...N hydrogen-bonding inter­actions in the packing, resulting in a complex three-dimensional network structure.
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