metal-organic compounds
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The title compound, [Na(C10H9.5N2O2S2)2(H2O)], is a molecular sodium complex with N′-(1,3-dithiolan-2-yl)-2-hydroxybenzohydrazide ligands with the negative charge spread evenly over both, and a water molecule. The NaI ion coordination is distorted trigonal–bipyramidal, formed by two N and three O atoms, with the NaI ion lying on a twofold rotation axis. Intramolecular N—HO hydrogen bonds occur. Molecules pack as discrete units and the crystal packing is stabilized by strong O—HO hydrogen bonds, which give rise to chains along [010]; the chains are interlinked by strong O—HO hydrogen bonds.