Bis­(4-benzoyl-3-methyl-1-phenyl-4,5-di­hydro-1H-pyrazol-5-olato-κ²O,O′)(methanol-κO)dioxidouranium(VI) methanol monosolvate

In the title compound, [U(C₁₇H₁₃N₂O₂)₂O₂(CH₃OH)]·CH₃OH, the U^VI ion is coordinated by seven O atoms in a distorted pentagonal–bipyramidal geometry with two 3-methyl-1-phenyl-4-benzoyl-4,5-dihydro-1H-pyrazol-5-olate groups with two O atoms in a bidentate chelating coordination mode and by three O atoms, one of which is from a methanol ligand. The crystal packing can be described by alternating layers of complex mol­ecules along the a axis. The structure is stabilized by O—H...N and O—H...O hydrogen bonding and van der Waals inter­actions.

Aqua­{4,4′-dimeth­oxy-2,2′-[pyridine-2,3-diylbis(nitrilo­methanylyl­idene)]­diphenolato}copper(II)

Mol­ecules of the title compound, [Cu(C₂₁H₁₇N₃O₄)(H₂O)], lie across a crystallographic mirror plane. The Cu^II atom is five-coordinated in a distorted square-pyramidal environment by two phenolate O atoms and two imine N atoms of the tetra­dentate Schiff base anion in the basal plane and one water mol­ecule in the apical position. Because of symmetry, the pyridine N atom and the corresponding C atom at the 4-position of the pyridine ring are disordered. The crystal packing can be described as being composed of alternating layers stacked along [001]. Intra­molecular C—H...N and inter­molecular C—H...O and O—H...O hydrogen-bonding inter­actions, as well as C—H...π and π–π stacking inter­actions [shortest centroid–centroid distance = 3.799 (8) Å and inter­planar distance = 3.469 (2) Å] are observed.