organic compounds
Open access
In the title compound, C18H18Cl2N2, the complete molecule is generated by the application of C2 symmetry. The C=N bond has an E configuration. The dihedral angle between the benzene ring and the 1,4-diazabutadiene plane is 66.81 (9)°.
metal-organic compounds
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In the cation of the title salt, [Ag(C12H6N2O2)2](C7H3N2O7), the AgI atom is coordinated in a distorted tetrahedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitrosalicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the AgI atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intramolecular O—HO hydrogen bond in the 3,5-dinitrosalicylate anion.
organic compounds
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In the crystal structure of the title compound, C18H13N5·H2O, adjacent molecules are linked by O—HN and N—HO hydrogen bonds, generating a chain propagating along [001].
organic compounds
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In the crystal structure of the title compound, C20H44NO2+·Br−, the cation and anion are connected via an O—HBr hydrogen bond, forming an ionic pair. The cation is disordered over two conformations related by a mirror plane, and the anion is situated on a mirror plane so that the asymmetric unit contains half of the ionic pair. The long alkyl chain in the cation adopts an all-trans conformation. The crystal packing exhibits weak intermolecular C—HO interactions.