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In the title compound, C18H18Cl2N2, the complete molecule is generated by the application of C2 symmetry. The C=N bond has an E configuration. The dihedral angle between the benzene ring and the 1,4-diaza­butadiene plane is 66.81 (9)°.

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In the cation of the title salt, [Ag(C12H6N2O2)2](C7H3N2O7), the AgI atom is coordinated in a distorted tetra­hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro­salicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the AgI atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intra­molecular O—H...O hydrogen bond in the 3,5-dinitro­salicylate anion.

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In the crystal structure of the title compound, C18H13N5·H2O, adjacent mol­ecules are linked by O—H...N and N—H...O hydrogen bonds, generating a chain propagating along [001].

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In the crystal structure of the title compound, C20H44NO2+·Br, the cation and anion are connected via an O—H...Br hydrogen bond, forming an ionic pair. The cation is disordered over two conformations related by a mirror plane, and the anion is situated on a mirror plane so that the asymmetric unit contains half of the ionic pair. The long alkyl chain in the cation adopts an all-trans conformation. The crystal packing exhibits weak inter­molecular C—H...O inter­actions.
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