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In the title compound, C18H18Cl2N2, the complete molecule is generated by the application of C2 symmetry. The C=N bond has an E configuration. The dihedral angle between the benzene ring and the 1,4-diaza­butadiene plane is 66.81 (9)°.

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The asymmetric unit of the title compound, C20H24N2, contains one half -mol­ecule which exhibits a crystallographically imposed center of symmetry. The benzene rings are inclined to the 1,4-diaza­butadiene mean plane by 78.3 (2)°.

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The title compound, C40H32N2, has crystallographic twofold rotation symmetry, with two C atoms lying on the axis. The dihedral angle between the two benzene rings of the 4-phenyl-2,6-dimethyl­phenyl group is 35.74 (17)°. The acenaphthene ring makes an angle of 76.93 (11)° with the benzene ring bonded to the N atom and an angle of 41.53 (13)° with the other benzene ring.
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