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Crystal structures of KLaS2, KPrS2, KEuS2, KGdS2, KLuS2, KYS2 and RbYS2, which belong to the α-NaFeO2 structural family (R \bar 3 m), have been determined as well as NaLaS2, which is derived from the disordered NaCl structural type (Fm\bar 3 m). The article is accompanied by a crystal-chemical analysis of group 1 and thallium(I) rare-earth sulfides as well as by a table that critically considers the published data of this class of compounds.

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The phase transitions of Zn2P2O7 were analyzed by differential scanning calorimetry and high-temperature single-crystal and powder X-ray diffraction.
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