Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Acta Cryst. (2012). B68, 602-609
https://doi.org/10.1107/S0108768112042577

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Dinuclear oxofluorometallates as a new structural type of d⁰ transition metal oxofluoride compound

A. A. Udovenko and N. M. Laptash

Two kinds of dimers in the crystal structures of A₃[M₂O_xF_11 - x]·(AF)_0.333 (A = K, Rb, NH₄; M = Nb, Mo, W; x = 2, 4) representing a new structural type of d⁰ transition metal oxofluoride compound are reported.

Keywords: dinuclear oxofluorometallates; vibrational spectra; bridging fluorine atoms; merohedral twins.

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Dinuclear oxofluorometallates as a new structural type of d0 transition metal oxofluoride compound

Dinuclear oxofluorometallates as a new structural type of d⁰ transition metal oxofluoride compound