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3-(4-Pyridyl)-acetylacetone (HacacPy) may be used as an N donor ligand in coordination chemistry and in thermal degradation, and its metal complex Fe(acacPy)3 can act as a poly(pyridine) bridge between two or three cations.

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Chain polymers crystallize from aqueous solutions of CaII and MnII halides with enantiopure or racemic alanine to form a series of closely related structure types.
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