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The title compound, tetra­carbonyl-1κ4C-tris­(tri­phenyl­phos­phino)-1κP,2κP,3κP-triangulo-chromiumdigold(AuAu)(2 CrAu) tetra­hydro­furan solvate, [Au2Cr(C18H15P)3(CO)4]·C4H8O, is a stable isolobal analogue of the extremely labile [(η2-H2)CrLn–1] molecular hydrogen complex (n = 6; L is a neutral ligand, e.g. CO or PPh3), and features the shortest known separation [2.6937 (2) Å] between two Au atoms in a triangular heteronuclear metal-cluster framework.
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