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Three cis nickel-di­thio­cyanate (SCN) complexes with different N,N'-bidentate bases have been prepared and their crystal structures determined: bis(2,2'-bi­pyridine-N,N')­bis­(thio­cyan-­ato-N)­nickel(II), [Ni(SCN)2­(C10H8N2)2], bis(1,10-phen­anthroline-N,N')­bis­(thio­cyanato-N)­nickel(II), [Ni(SCN)2­(C12H8N2)2], and bis(2,9-di­methyl-1,10-phenanthroline-N,N')­bis­(thiocyanato-N)nickel(II) mono­hydrate, [Ni(SCN)2­(C12H8N2)2]·H2O. Distortions due to ligand size are discussed.
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