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The crystal structure of Pb5.0(1)In8.4(1)Bi1.6(1)S20, a compositional variant of a new quaternary sulfide phase, is closely related to the structures of a ternary and another quaternary phase with very different Pb:Bi ratios.

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The structure of the compound Pb4.94(3)In3.05(3)Bi4.99(3)S17, a compositional variant of a new quaternary sulfide phase, is closely related to that of Pb4In3Bi7S18.
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