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The synthesis and crystal structure of the new title chiral Schiff base, C16H16N2O4, derived from the condensation of L-phenyl­alaninol [(S)-(-)-2-amino-3-phenyl-1-propanol] and 5-nitro­salicylaldehyde (2-hydr­oxy-5-nitro­benzaldehyde), are presented. There are two molecules in the asymmetric unit and they are stabilized in the solid state in the NH tautomeric form.
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