Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ³N,S:S;κ³S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]

The dinuclear title complex, [Ag₂(C₆H₇N₂S)₂(C₁₈H₁₅P)₂], comprises two inversion-related [Ag(C₆H₇N₂S)(C₁₈H₁₅P)] units. The pyrimidine­thiol­ate anion acts both as a bridging and a chelating ligand. The Ag^I ions are linked via two μ₂-S donor atoms, which generate a strictly planar Ag₂S₂ core with an Ag...Ag separation of 2.9569 (4) Å. The Ag^I ion presents a distorted tetra­hedral coordination geometry. In the crystal, weak C—H...N and C—H...S hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (010).