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The title co-crystal, C4H7N5·C4H10O2, crystallizes with one mol­ecule of 6-methyl-1,3,5-triazine-2,4-diamine (DMT) and one mol­ecule of butane-1,4-diol in the asymmetric unit. The DMT mol­ecules form ribbons involving centrosymmetric R22(8) dimer motifs between DMT mol­ecules along the c-axis direction. These ribbons are further hydrogen bonded to each other through butane-1,4-diol, forming sheets parallel to (121).
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