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metal-organic compounds
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In the title compound, [Sn2(C4H9)4(C6H6PO3)4]n, the basic unit is a dimer containing two symmetry-related SnIV atoms bridged by two hydrogenphenylphosphonate anions. This fragment is located about an inversion center, and each SnIV atom is linked to two other hydrogenphenylphosphonate anions, giving a layered structure parallel to (010). The coordination geometry for the SnIV atoms is close to octahedral. The layers are connected via O—H
O hydrogen bonds, generating a three-dimensional network. One butyl group is disordered over two sets of sites, with occupancies of 0.49 (2) and 0.51 (2).
O hydrogen bonds, generating a three-dimensional network. One butyl group is disordered over two sets of sites, with occupancies of 0.49 (2) and 0.51 (2).organic compoundsOpen access
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In the title salt, [(CH3)2CH]2NH2]+·[C6H5PO2(OH)]−, the anions are linked by pairs of O—HO hydrogen bonds, forming inversion dimers. These dimers are bridged by the cations via N—HO hydrogen bonds, leading to a three-dimensional structure.
O hydrogen bonds, forming inversion dimers. These dimers are bridged by the cations via N—HO hydrogen bonds, leading to a three-dimensional structure.
