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The binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu...Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII cation is coordinated by four carboxyl­ate O atoms from four 4-azido­benzoate ligands, and one O atom from a dimethyl­formamide mol­ecule, forming an overall distorted octahedral geometry when the Cu...Cu bond is also considered.
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