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The heteroleptic cuprous complex [Cu(POP)(CH3CN)(4-PBO)]PF6, where POP is the diphosphane ligand {2-[2-(di­phenyl­phosphan­yl)phen­oxy]phen­yl}di­phenyl­phosphane and 4-PBO is the N-containing ligand 2-(pyridin-4-yl)-1,3-benzoxazole, displays a CuP2N2 distorted tetra­hedral coordination geometry. The electronic absorption, photoluminescence and thermal stability properties of this complex have been studied. A yellow emission band is attributed to an excited state resulting from metal–ligand charge transfer.
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