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In a one-dimensional coordination polymer prepared from the direct reaction of 2-(hy­droxy­methyl)pyridine with Cu(OAc)2·H2O (OAc is acetate), four Cu centres are bridged by four O atoms from discrete (pyridin-2-yl)methanol­ate ligands and two acetate groups, forming a capped [Cu4O4] cubane core. Each core is doubly bridged to each of two adjacent cores by [N(CN)2] anions, resulting in one-dimensional chains.
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