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A novel two-dimensional cobalt(II) complex, composed of one-dimensional twisted pair-like {[Co(2,5-PDC)2]2−}n chains interlinked by cationic [Co(H2O)4]+ units, is extended into a three-dimensional supra­molecular structure by hydrogen bonding involving uncoordinated water mol­ecules.

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A novel infinite two-dimensional cadmium(II) polymer and a one-dimensional cobalt(II) polymer constructed by benzene-1,4-di­carboxyl­ate ligands are formed. The two complexes are finally assembled to form three-dimensional network structures.
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