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In the title compound, {[Co(C14H8N2O5)(C10H8N2)]·3H2O}n, the CoII cation is five-coordinated with a slightly distorted trigonal–bipyramidal geometry, and the 5-isonicotinamido­isophthalate ligands link CoII atoms into a layered structure. These two-dimensional arrays are further pillared by rod-like 4,4′-bipyridine ligands to give a three-dimensional framework with pcu (primitive cubic) topology. The magnetic and adsorption properties of the title compound are also discussed.
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