metal-organic compounds
A novel one-dimensional CuII coordination polymer, catena-poly[bis(μ4-3-{[2-(3-hydroxy-2-oxidobenzylidene)hydrazinylidene]methyl}benzene-1,2-diolato)dimethanoltricopper(II)], [Cu3(C14H10N2O4)2(CH3OH)2]n, (I), was constructed with a di-Schiff base supported centrosymmetric trinuclear CuII subunit. In the subunit, two peripheral symmetry-related CuII cations have square-pyramidal CuNO4 geometry and the central third CuII cation lies on an inversion centre with octahedral CuN2O4 geometry. In (I), each partially deprotonated di-Schiff base 3-{[2-(3-hydroxy-2-oxidobenzylidene)hydrazinylidene]methyl}benzene-1,2-diolate ligand (Hbcaz3−) acts as a heptadentate ligand to bind the CuII centres into chains along the a axis. A centrosymmetric Cu2O2 unit containing an asymmetrically bridging O atom, being axial at one Cu atom and equatorial at the other Cu atom, links the trinuclear CuII subunit into a one-dimensional chain, which is reinforced by intramolecular phenol–methanol O—HO and methanol–phenolate O—HO hydrogen bonds. Interchain π–π stacking interactions between pyrocatechol units, with a distance of 3.5251 (18) Å, contribute to the stability of the crystal packing.