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In the title complex, [Zn(C12H6O4)(H2O)]n, a ZnII polymer based on naphthalene-1,8-dicarboxyl­ate (1,8-nap), the ZnII atoms adopt an elongated octa­hedral coordination geometry. A zigzag chain is formed by μ2-aqua ligands and μ2-carboxyl­ate groups of the 1,8-nap ligands. Adjacent parallel chains are further linked by 1,8-nap ligands, forming a twisted two-dimensional layer structure along the (100) plane.
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