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organic compounds
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In the title compound, C13H8BrClOS, the thiophene and phenyl rings are inclined by 40.69 (11)° to each other. The crystal structure is characterized by C—H
π interactions, which link the molecules into broad layers parallel to (100). Short BrCl contacts [3.698 (1) Å] link these layers along [100].
π interactions, which link the molecules into broad layers parallel to (100). Short BrCl contacts [3.698 (1) Å] link these layers along [100].organic compoundsOpen access
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In the title compound, C16H17NO3S2, the dihedral angles between the O/C/C/S group and the 2H-chromene ring system and the thiocarbamate group are 14.46 (9) and 83.30 (9)°, respectively. The bond-angle sum at the N atom is 360.0°. One of the methyl C atoms lies above the thiocarbamate plane and one lies below it [deviations = 1.264 (3) and −1.147 (3) Å, respectively]. In the crystal, inversion dimers linked by pairs of C—HO hydrogen bonds generate R22(10) loops. Weak aromatic π–π stacking interactions [shortest centroid–centroid distance = 3.8138 (11) Å] are also observed.
O hydrogen bonds generate R22(10) loops. Weak aromatic π–π stacking interactions [shortest centroid–centroid distance = 3.8138 (11) Å] are also observed.
