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The asymmetric unit of the title compound, C44H32P2, conventionally abbreviated BINAP, is one half of the complete chiral BINAP mol­ecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the mol­ecule in two identical halves; a center of symmetry between mol­ecules further determines the racemic pairs. There are no obvious supra­molecular inter­actions between adjacent BINAP mol­ecules.
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