organic compounds
Open access
In the title compound, C13H17NO3·0.5H2O, a new caffeic acid amide derivative, the solvent water molecule lies on a twofold axis and the terminal ethyl group appears disordered with occupancy factors of 0.525 (6) and 0.475 (6). The benzene ring makes an angle of 17.3 (2)° with the C=C—C—O linker. The presence of an ethylenic spacer in the caffeic acid amide molecule allows the formation of a conjugated system, strongly stabilized through π-electron delocalization. The C=C double bond in the linker is trans, similar to those previously reported in caffeic esters. The crystal is stabilized by O—HO, N—HO and C—HO hydrogen bonds. The molecules of the caffeic acid amide form a supermolecular planar structure through O—HO hydrogen bonds between a hydroxy group of one caffeic acid molecule and a carbonyl O atom of another. These planes interact via C—HO, O—HO and N—HO hydrogen bonds to form a three-dimensional network.