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The title compound, [Cu(C10H8N2)(H2O)3](C20H10O7S2·2H2O, was obtained by a hydro­thermal route. The asymmetric unit contains one copper complex cation including three coordinated water molecules, one organic anion, three coordinated water mol­ecules and two uncoordinated water mol­ecules. The CuII atom exists in a distorted square-pyramidal geometry. Face-to-face offset π–π stacking and inter­molecular hydrogen-bond inter­actions generate a three-dimensional supramolec­ular array.
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