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The title compound, C12H20N4O2S, has been synthesized for use as an inter­mediate for antihypertensive agents, potential antimalarials and mol­ecular rectification materials. The inter­molecular S...N non-bonded separation within a column in the crystal structure is 3.308 (2) Å, indicating a strong inter­molecular inter­action between the cyano groups and the S atoms. Attractive C—H...O hydrogen bonds are responsible for zigzag mol­ecular chains propagating in the a-axis direction; these types of inter­molecular inter­actions combine to form an extended three-dimensional network in the lattice.

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The title compound, C10H14N2O5S3, has been synthesized as a key inter­mediate in the synthesis of topically active carbonic anhydrase inhibitor MK-0507. N—H...O hydrogen bonds are responsible for the formation of centrosymmetric dimers and zigzag mol­ecular chains. The inter­molecular non-bonded S...O separation in the crystal structure is 3.415 (2) Å, indicating a strong inter­molecular inter­action between the amino­sulfonyl and S-dioxide groups.
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