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The title compound, [Cu(C10H9N3)2(CH3OH)2](SiF6), was obtained in low yield in the reaction of dipyridylamine with Cu(BF4)2 using thermal conditions in a sealed pressure tube. The Cu-based cation lies at the centre of the triclinic unit cell, the hexa­fluoro­silicate anions lying at the corners. Cations and anions, which are centrosymmetric, are held together by hydrogen bonds.
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