Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Double complexes [Co(NH₃)₅(H₂O)]₂[Zr₃F₁₈]·6H₂O and [Co(NH₃)₆]₂[Zr₃F₁₈]·6H₂O

The structures of the title compounds are built from octahedral [Co(NH₃)_x(H₂O)_y]³⁺ cations and [Zr₃F₁₈]⁶⁻ anionic chains. O—H

F hydrogen bonds help to establish the crystal packing.

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Double complexes [Co(NH3)5(H2O)]2[Zr3F18]·6H2O and [Co(NH3)6]2[Zr3F18]·6H2O