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The structure of the title compound consists of layers of [Ru2Cl10O]4− and [Ba(H2O)7]2+ ions alternating along the c axis. The overall structure is held together by O—H...O hydrogen bonds and O—H...Cl dipole–dipole inter­actions.

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The structure of the title compound, (C10H12N2)[SnF3]2, is made up of alternating layers of cations and anions, where the anion layers form extended polymeric sheets through a series of secondary Sn...F bonds. Strong N—H...F hydrogen bonds crosslink adjacent cation and anion layers, thereby building a three-dimensional network.
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