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In the title compound, C23H19N5O6·H2O, the two components are linked into complex chains by a combination of two independent O—H...O and two independent N—H...O hydrogen bonds. The complex chains are linked into a two-dimensional sheet network via π–π stacking inter­actions and C—H...O hydrogen bonds.

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In the title compound, [Nd2(C4H4O4)2(C2O4)(H2O)2]n, the flexible succinate anion assumes the gauche conformation and bridges the nine-coordinate Nd atoms to generate two-dimensional layers parallel to (010). The coordination polymer layers are linked into a three-dimensional framework by the rigid oxalate ligands. The oxalate ions are located on a center of inversion.
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