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In the title complex, {[Mn(C4O4)(C10H8N2)(H2O)]·H2O}n, each MnII ion has a distorted octa­hedral coordination formed by two N atoms of a 2,2′-bipyridine ligand, three carboxyl O atoms of three different acetyl­ene­dicarboxyl­ate ligands and one coordinated water mol­ecule. The acetyl­ene­dicarboxyl­ate ligands act in a tridentate mode connecting adjacent MnII ions and constructing a two-dimensional structure which can be regarded as an unusual plywood-like stacked network.
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