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The structure of the title compound, C38H56N8S2·2C2H6OS, has been determined by single-crystal diffractometry and is compared with the structures of other compounds containing the thio­semicarbazide group. The structure is stabilized by N—H...S hydrogen bonding, resulting in the formation of infinite chains parallel to the [010] axis. The thio­semicarbazone group has an E configuration.

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The title compound, C20H29NOS, the thio­morpholine ring adopts a chair conformation. The crystal structure is stabilized by inter­molecular C—H...π inter­actions.
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