metal-organic compounds
The tetradentate Schiff base carboxylate-containing ligand bis(2-pyridylmethyl)amino-6-caproic acid (Hpmca) reacts with zinc(II) perchlorate to give the title one-dimensional zinc(II) complex, {[Zn(C18H22N3O2)(H2O)](ClO4)}n or {[Zn(μ-pmca)(H2O)](ClO4)}n. Each ZnII ion has a distorted octahedral geometry, being coordinated by three N atoms of the ligand, two O atoms belonging to another ligand, and one water molecule.