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The tetra­dentate Schiff base carboxyl­ate-containing ligand bis­(2-pyridylmeth­yl)amino-6-caproic acid (Hpmca) reacts with zinc(II) perchlorate to give the title one-dimensional zinc(II) complex, {[Zn(C18H22N3O2)(H2O)](ClO4)}n or {[Zn(μ-pmca)(H2O)](ClO4)}n. Each ZnII ion has a distorted octa­hedral geometry, being coordinated by three N atoms of the ligand, two O atoms belonging to another ligand, and one water mol­ecule.
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