organic compounds
Two independent ion pairs comprise the asymmetric unit of the title compound, C6H16N+·C18H14ClN2O2−. The pyrazole ring, the methylbenzene ring and the chlorobenzene ring are each essentially planar. The dihedral angles between the two benzene rings are 97.6 (3) and 97.1 (3)° for the two anions. Weak N—HO interactions are observed in the crystal structure.
organic compounds
In the title compound, C22H15ClN2O2, the molecular structure is stabilized by intramolecular C—HO and C—HN hydrogen bonds. Intermolecular C—HO hydrogen bonds link the molecules into dimers.
organic compounds
The title compound, C18H15ClN2O2, contains planar pyrazole, tolyl and chlorophenyl rings. Intermolecular C—HO hydrogen bonds link the molecules into dimers. The carbonyl O atom is found to be disordered.
organic compounds
The molecular structure of the title compound, C16H9BrF4N2O3S, is stabilized by an intramolecular C—HO hydrogen bond. In the crystal structure, supramolecular layers are formed parallel to the bc plane by an intermolecular C—HF hydrogen bond. The CF3 group was found to be disordered.