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Two independent ion pairs comprise the asymmetric unit of the title compound, C6H16N+·C18H14ClN2O2. The pyrazole ring, the methyl­benzene ring and the chloro­benzene ring are each essentially planar. The dihedral angles between the two benzene rings are 97.6 (3) and 97.1 (3)° for the two anions. Weak N—H...O inter­actions are observed in the crystal structure.

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In the title compound, C22H15ClN2O2, the mol­ecular structure is stabilized by intra­molecular C—H...O and C—H...N hydrogen bonds. Inter­molecular C—H...O hydrogen bonds link the mol­ecules into dimers.

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The title compound, C18H15ClN2O2, contains planar pyrazole, tolyl and chloro­phenyl rings. Inter­molecular C—H...O hydrogen bonds link the mol­ecules into dimers. The carbonyl O atom is found to be disordered.

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The mol­ecular structure of the title compound, C16H9BrF4N2O3S, is stabilized by an intra­molecular C—H...O hydrogen bond. In the crystal structure, supramolecular layers are formed parallel to the bc plane by an inter­molecular C—H...F hydrogen bond. The CF3 group was found to be disordered.
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