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The title compound, C4H8N2O, crystallizes from the vapor phase in sheets supported by a one-dimensional hydrogen-bonded network. The mol­ecular unit shows planar ureido -NCH3 groups, but the slight out-of-plane hydrogen-bond geometry may be indicative of some pyramidalization of the ureido -NH groups.

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The title compound, C21H24O8, crystallizes as colorless needles composed of a racemic mixture that adopts the packing order of columns of alternating enanti­omers, all of whose oxirane rings are essentially aligned. Within each column, the carbonyl groups of adjacent enanti­omers are oriented in nearly opposite directions. The structure is stabilized by several C—H...O associations.
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