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The asymmetric unit of the title compound, [Ru(OH)(NH3)4(NO)][Pd(NO2)4]·H2O, consists of one complex [Ru(NO)(NH3)4OH]2+ cation, two half [Pd(NO2)4]2- complex anions, each anion located on an inversion centre, and a water mol­ecule of crystallization. The crystal structure exhibits an extensive hydrogen-bonding network.
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