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The title compound, C21H13FO, was prepared from anthrone and 4-fluoro­benz­aldehyde. The central six-membered ring has an asymmetric boat conformation, in which the carbonyl C and the opposite C atom deviate from the plane of the other four atoms by 0.173 (2) and 0.319 (2) Å, respectively.

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The central six-membered ring of the title compound, C28H24N4O4S2, has a boat conformation, in which the N atoms bonded to sulfonyl groups deviate from the plane of the other four atoms by 0.389 (4) and 0.343 (4) Å.

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The title compound, C24H30N6O2, crystallizes with two mol­ecules in the asymmetric unit, both lying on twofold rotation axes. In both mol­ecules, the central tetrazine ring adopts a boat conformation.
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