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The structure of the title compound, C9H9BrN3+·Br-·H2O, was determined at 150 K. It is a supramolecular adduct of imidazolium bromide and water mol­ecules. Helical chains of (H2O·Br-) exist in the structure along the [001] direction. Each chain forms extensive hydrogen bonds with the imidazolium cations.

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The structure of the title compound, [W2(C4H9N)4(C7H11N2)(C4H10NO)O], was determined at 150 K. It is an asymmetrical binuclear compound with a μ-oxo bridge linking two tungsten(VI) centers.
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