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The title compound, C8H9N3OS, crystallizes in a triclinic unit cell, with two crystallographically independent mol­ecules in the asymmetric unit. It has a two-dimensional layer structure with intermolecular hydrogen bonding.

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In the title compound, 4-amino-N-(6-chloro-3-pyridazin­yl)­benzene­sulfonamide, C10H9ClN4O2S, the pyridazine ring and the benzene ring form a distorted V configuration, with a dihedral angle of 82.86 (6)°. The crystal packing is stabilized by π–π stacking inter­actions between the pyridazine rings and inter­molecular N—H...O, C—H...O and C—H...N hydrogen bonds, linking the mol­ecules into a two-dimensional network.

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In the title complex, diaqua­bis(2-amino-3-methyl­butyrato-κ2N,O)nickel(II), [Ni(C5H10NO2)2(H2O)2], the NiII atom (site symmetry 2) is octa­hedrally coordinated by two N,O-bidenate valinate ions and two water mol­ecules. A network of inter­molecular hydrogen bonds links the complex mol­ecules into a two-dimensional network.
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