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The title compound, C10H7NO3, has the cyano, carboxyl­ic acid and phenol groups in a trans configuration with respect to the C=C double bond. Intramolecular O—H...N and eight-membered O—H...O hydrogen-bonding interactions form an infinite two-dimensional layer structure.

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In the title compound, C12H10N2·H2O, inter­molecular O—H...N hydrogen bonds are highly effective in forming a one-dimensional chain. In addition, the presence of C—H...O hydrogen bonds helps to build a three-dimensional supramolecular network, thereby stabilizing the crystal structure.
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