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In the title coordination polymer, {[Li(C2H5NO2)2(H2O)]Br}n, the Li+ cation is coordinated by three carboxyl­ate O atoms of zwitterionic glycine mol­ecules and by a water mol­ecule, forming a distorted tetra­hedral geometry. One of the two glycine mol­ecules bridges neighbouring complexes, forming an infinite chain parallel to the c axis. Polymeric chains are further linked by extensive hydrogen bonds involving the Br anions and glycine and water mol­ecules, producing a three-dimensional network.
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